I have a 2007 GTI 2.0t FSI bought in Nov. 2006. So, I have been dealing with this subject for over thirteen years on the MK5. I did a treatment with BG44k, and another with CRC at 60k and 90k miles. At 120k miles, I thought to look up the MSDS for each of those products as well as a couple of others including SeaFoam. Finding in them there was on average of about 25%-30% solvents of different sorts...NAPHTHA, Xylene, mineral spirits, etc..
Since I knew the valves were clean...I thought it would make much more sense to give it a blow-by more often so to keep them clean. Wouldn't it be better to keep the valves clean rather than try knocking off a bunch of it. What it is really missing is fuel. The last 5 to 6 years, I only drive the MK5 about 4k miles per year and I do the oil change each June. So, since it was at 120k miles, I have been doing the blow-by each year just before I do the oil change. I use a fuel to solvent solution ratio of 11:1, or "11oz fuel to 1oz NAPHTHA or Xylene". When I come home after it has been run and heated up, I do the blow-by if I feel like doing it that day...and I am also planning to do the oil change real soon. After injecting the fluid and replace the IAT sensor, I keep it at near 2k rpm for near ten minutes followed by a 10 minute drive keeping it as close to 3k rpm as much as possible.
I agree with everyone that the best way to clean major build-up is by blasting or "soaking&scraping" and I mention this in my vid description. I am also aware of the concerns of dislodged bits of carbon passing through the combustion, turbo, and catalyst...and why I recommend using an endo-scope followed by a blast or scrape job first. It is your risk, I just chose to come up with a less intrusive service and something that will hopefully keep them clean.
Here's my vid, but I have switched to a different tip/nozzle since the one I found was made for a finer mist when spraying.
Here are pics of before
https://flic.kr/p/Wp9o7p
after
https://flic.kr/p/Wp9o1H
The pics are from the first time I did this. Yes, those other methods will clean more of the carbon off, but remember, this was the first time at 80k miles. So, to see the valve guides and valve stems with just one blow-by was remarkable in my mind. Pic quality is due to a cheap $10 endo...newer one with better quality and lighting is to be ordered soon. Again, the vid;