Short drives and lots of throttle changes causes a rich FA mix which is what leaves the gunk on the backs of the valves.
I kinda think a good long drive (3-4 hrs) at 70-75 is good for cleaning a lot of material off the backs of the valves. The fuel mix will lean out, the valves and head will become super heated by the constant run speed and lean mix, and the carbon will begin to atomize off the backs of the valves and possibly from the head ports too.
Actually this is not the case. Here is a good piece of information which helps to explain why. Hope this helps.
The main reason is that fuel and added detergents are not hitting the back of the intake valves. By injecting the fuel directly into the cylinder instead of at the back of the valve, the gasoline and detergents can’t clean the valve and port.
Second, leaner mixtures and higher combustion pressures can make the problem worse over time. A direct fuel injection motor produces more energy from a given amount of fuel and air than a port fuel injection engine. Today’s engines operate on a ragged edge between optimal efficiency and a misfire. There is not much room for error, like hot spots in the combustion chamber or a worn spark plug.
When a hot spot or sub-optimal flame front is created due to turbulent air, the amount of unburned fuel in the combustion chamber increases. When the valve opens during the intake stroke, it might come in contact with these byproducts, and, unlike the exhaust valve, the gases passing by are not hot enough to burn them off.
Third, the intake valve goes into the combustion chamber, regardless of whether it is port fuel injected or direct injected. When it does, for that small period of time, the valve is exposed to combustion byproducts that can stick to its neck. If the previous combustion cycle was less than optimal, the intake valve is exposed.
Some direct-injection vehicles with variable valve timing can expose the valve to combustion byproducts as the valves adjust, which creates a scavenging effect to either pull or leave behind a small amount of exhaust gases in the chamber to control NOX emissions. Also, some turbocharged direct-injection engines will leave the intake and exhaust valves open at the same time in order to keep the turbo spinning to reduce lag.